Camikaze wrote:Havin a stab at the science thingo here but I guess bigger diameter = more heat thrown at it = more vapour in column = the ability to condense more product over a given time.
MacStill wrote:it's all about throughput, less restrictions the better :handgestures-thumbupleft:
db1979 wrote:A bubbler follows very similar principles to column chromatography that I used to do a few years back in a research lab.
You start with the mixture you want to separate at the top of the column and add solvent which then causes the mixture to interact with the solid phase and the liquid phase. Essentially the components of the mixture move down the column based on how they interact with both the solvent and the solid phase, some prefer to spend more time stuck to the solid phase while others spend more time dissolved in the solvent. The wider the column, the less height they take up in the column and therefore you're able to separate a larger amount of mixture with a wider column. Try to separate a large amount with a narrow column and the components get spread out over a larger height and you get smearing (overlapping). The only difference between a liquid-solid chromatography column to a bubbler is that a bubbler separates based on boiling point (and components move up, not down the column).
I agree with blonde about the speed of a pot still, since gases are highly compressible you can get a bucket load of gas going through a small constriction but you need a lot of energy to push it through (in a pressured gas cylinder that energy comes from the volume of pressurised gas). We're not trying to do that with a bubbler though, we are looking at separating components in the wash and a wider column will allow more loading and therefore more hearts can move through the column at the one time. So take off speed is a function of how much separation (compression) you want between heads, hearts and tails and this is dependent on column diameter - for a given energy input.
So jonno, go for 4 inch if you can get some.
MacStill wrote:So are we talking about stripping ? if the answer is yes, refer to my previous comment ;-)
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