Found this
Carbonate and Bicarbonate
Carbonate and bicarbonate could be present in your brewing water, but bicarbonate is most likely the unit you’ll need to adjust. Bicarbonate acts as a “buffer” against pH change. Water with high bicarbonate levels has high “buffering capacity” and is more resistant to pH change. Conversely, water with low buffering capacity (reverse osmosis water, for example) will have almost no buffering agents and may be more susceptible to pH change during the mash. Depending on the style of beer you’re brewing you may need to increase or decrease buffering capacity, which will be explained below.
Base malts and lighter colored grains lower pH of the mash slighlty. Darker roast, specialty malts tend to lower mash pH a lot. In general, mash pH should be anywhere from 5.2 to 5.6 (measured at least 15 minutes after grain has been added to the brewing water). This means that if you brew a stout with reverse osmosis (RO) water, mash pH will likely drop below the ideal range due to the low buffering capacity of the water and the acidity of the dark roasted grains), the resulting beer tends to take on a harsh “grainy” taste with less body. To counteract the acidity of specialty grains, increase pH by adding baking soda.
The easiest way to reduce bicarbonate levels is to cut your tap (or well) water with distilled water at a ratio of 1:1. This will roughly reduce bicarbonate levels by half. Be aware, this will also reduce levels of other minerals in your brewing water.
Calculating pH increases is more complicated than the adjustments listed above and the use of a water calculator, such as BeerSmith or Brewer’s Friend (an online calculator), is suggested. The easiest way to adjust pH is to brew the beer, measure the pH of the mash (during the brew day) and add a bit of baking soda or distilled water for the next batch.
Seems bicarb is needed to prevent ph crash while carbonate dictates ph. Anyone have a copy of Gympie area water report I can have a look at? I have contacted council in the mean time see If I can get one..
would explain why ph is fine at start then crashs to shit..